A Highly Efficient Heterogenized Iridium Complex for the Catalytic Hydrogenation of Carbon Dioxide to Formate
- Authors
- Park, Kwangho; Gunasekar, Gunniya Hariyanandam; Prakash, Natarajan; Jung, Kwang-Deog; Yoon, Sungho
- Issue Date
- Oct-2015
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- covalent triazine framework; formic acid; heterogenized catalysts; hydrogenation; iridium
- Citation
- CHEMSUSCHEM, v.8, no.20, pp 3410 - 3413
- Pages
- 4
- Journal Title
- CHEMSUSCHEM
- Volume
- 8
- Number
- 20
- Start Page
- 3410
- End Page
- 3413
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45729
- DOI
- 10.1002/cssc.201500436
- ISSN
- 1864-5631
1864-564X
- Abstract
- A heterogenized catalyst on a highly porous covalent triazine framework was synthesized and characterized to have a coordination environment similar to that of its homogeneous counterpart. The catalyst efficiently converted CO2 into formate through hydrogenation with a turnover number of 5000 after 2h and an initial turnover frequency of up to 5300h(-1); both of these values are the highest reported to date for a heterogeneous catalyst, which makes it attractive toward industrial application. Furthermore, the synthesized catalyst was found to be stable in air and was recycled by simple filtration without significant loss of catalytic activity.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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