Bis(4-aminopyridine){2,2′-[1,2-phenylenebis(nitrilomethanylylidene)] diphenolato}cobalt(III) nitrateopen access
- Authors
- Dharmalingam, Sivanesan; Yoon, Sungho
- Issue Date
- Sep-2013
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.69, no.9, pp m495 - m496
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 69
- Number
- 9
- Start Page
- m495
- End Page
- m496
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45833
- DOI
- 10.1107/S1600536813020953
- ISSN
- 1600-5368
- Abstract
- In the title compound, [Co(C20H14N2O 2)(C5H6N2)2]NO 3, the CoIII atom is coordinated in a slightly elongated octahedral geometry by the N2O2 donor set of the tetradentate Schiff base ligand and by the pyridine N atoms of two trans-arranged monodentate 4-aminopyridine molecules. The pyridine rings are aligned nearly perpendicularly to each other [dihedral angle = 82.28 (13)°]. The phenoxy rings form dihedral angles of 12.37 (12) and 12.16 (14)° with the phenylene ring. In the crystal, N - H⋯O and C - H⋯O hydrogen bonds link the ions into a three-dimensional network. © 2013 Dharmalingam and Yoon et al.
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