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Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH
- Authors
- Sivanesan, Dharmalingam; Yoon, Sungho
- Issue Date
- Jul-2013
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- NADH regeneration; Indirect electrochemical method; Chemical method; Crystal structure
- Citation
- POLYHEDRON, v.57, pp 52 - 56
- Pages
- 5
- Journal Title
- POLYHEDRON
- Volume
- 57
- Start Page
- 52
- End Page
- 56
- ISSN
- 0277-5387
1873-3719
- Abstract
- A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [eta(5)-Cp*Rh(bpy-OH)ClICI complex at 771 mV (versus Ag/AgCI) or chemically with formate, transformed NAD(+) efficiently into NADH with a TOF = 710 at 60 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.
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