Bis(μ-4,4″-difluoro-1,1′:3′,1″-terphenyl- 2′-carboxylato-k2O:O′)bis[aqua(4,4″-difluoro-1, 1′:3′, 1″-terphenyl-2′-carboxylato-kO)(pyridine-kN) cobalt(II)] diethyl ether disolvateopen access
- Authors
- Kim, Namseok; Yoon, Yeahsel; Lee, Ha-Jin; Yoon, Sungho
- Issue Date
- Oct-2012
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.68, no.10, pp m1264 - m1265
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 68
- Number
- 10
- Start Page
- m1264
- End Page
- m1265
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/45967
- DOI
- 10.1107/S1600536812038391
- ISSN
- 1600-5368
- Abstract
- The structure of the title compound, [Co2(C19H 11F2O2)4-(C5H 5N)2(H2O)2]·2C 4H10O, comprises two CoII atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co···Co separation of 3.1923 (15) Å. Each Co2+ cation is coordinated by three O atoms of three 4,4″-difluoro-1,1′:3′,1″-terphenyl-2′-carboxylate ligands, one water O atom and one pyridine N atom, forming a CoO4N polyhedron. Strong intramolecular O-H···O hydrogen bonds are observed between terminal metal-bound carboxylate groups and water O atoms.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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