Dichloridobis(2-phenyl-pyridine-κN)zinc(II)open access
- Authors
- Dharmalingam, Sivanesan; Lee, Ha-Jin; Yoon, Sungho
- Issue Date
- Apr-2012
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.68, no.4, pp m431 - m432
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 68
- Number
- 4
- Start Page
- m431
- End Page
- m432
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/46006
- DOI
- 10.1107/S1600536812010616
- ISSN
- 1600-5368
- Abstract
- In the title compound, [ZnCl 2(C 11H 9N) 2], the Zn 2+ cation lies on a twofold axis and is coordinated by two Cl - anions and the N atoms of two 2-phenyl-pyridine ligands, forming a ZnN 2Cl 2 polyhedron with a slightly distorted tetra-hedral coordination geometry. The dihedral angle between the phenyl ring and the metal-bound pyridine ring is 50.3 (4)° for each 2-phenyl-pyridine ligand. This arranges the phenyl ring from one ligand in the complex above the pyridine ring of the other resulting in an intra-molecular π-π inter-action, with a centroid-centroid distance of 3.6796 (17) Å. Weak C-H⋯Cl hydrogen bonds stabilize the crystal packing, linking mol-ecules into chains along the c axis.
- Files in This Item
-
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/46006)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.