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Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries

Authors
Kim, HyunjungHan, ByungheeChoo, JaebumCho, Jaephil
Issue Date
Dec-2008
Publisher
WILEY-V C H VERLAG GMBH
Keywords
anode materials; gels; lithium; nanostructures; silicon
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.47, no.52, pp 10151 - 10154
Pages
4
Journal Title
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume
47
Number
52
Start Page
10151
End Page
10154
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/46945
DOI
10.1002/anie.200804355
ISSN
1433-7851
1521-3773
Abstract
(Figure Presented) Particle-larly good! Thermal annealing and etching of physical composite butyl-capped Si gels and SiO2 nanoparticles at 900°C under an Ar atmosphere is a versatile method for the formation of 3D porous bulk Si particles (see picture). Complete etching of the SiO2 from the SiO2/carbon-coated Si (c-Si) composite results in the retention of the remaining c-Si as a highly porous but interconnected structure, which preserves the starting morphology. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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