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Colorimetric determination of Cu2+ in simulated wastewater using naphthalimide-based Schiff base

Authors
Chang, In JungChoi, Myung GilJeong, Yong AeLee, Sang HunChang, Suk-Kyu
Issue Date
Feb-2017
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Cu2+ ion; 3-Hydroxynaphthalimide; Diaminomaleonitrile; Colorimetry; Liquid-liquid extraction; Smartphone
Citation
TETRAHEDRON LETTERS, v.58, no.5, pp 474 - 477
Pages
4
Journal Title
TETRAHEDRON LETTERS
Volume
58
Number
5
Start Page
474
End Page
477
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/4813
DOI
10.1016/j.tetlet.2016.12.066
ISSN
0040-4039
Abstract
A new Cu2+-selective colorimetric sensor was developed by combining the chromophore 3-hydroxynaphthalimide with diaminomaleonitrile. The sensor showed Cu2+-selective colorimetric signaling behavior in dimethylsulfoxide, indicated by a solution color change from yellow to pink, which was readily discernible without any external devices. Practical application of the sensor to the detection of Cu2+ in an aqueous solution containing other environmentally relevant metal ions by selective two-phase liquid-liquid extraction with ethyl acetate was possible. Particularly, extractive signaling of Cu2+ in simulated semiconductor wastewater with a readily-usable smartphone as a colorimetric data capture and analysis tool was successfully conducted. (C) 2016 Elsevier Ltd. All rights reserved.
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