Colorimetric determination of Cu2+ in simulated wastewater using naphthalimide-based Schiff base
- Authors
- Chang, In Jung; Choi, Myung Gil; Jeong, Yong Ae; Lee, Sang Hun; Chang, Suk-Kyu
- Issue Date
- Feb-2017
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Cu2+ ion; 3-Hydroxynaphthalimide; Diaminomaleonitrile; Colorimetry; Liquid-liquid extraction; Smartphone
- Citation
- TETRAHEDRON LETTERS, v.58, no.5, pp 474 - 477
- Pages
- 4
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 58
- Number
- 5
- Start Page
- 474
- End Page
- 477
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/4813
- DOI
- 10.1016/j.tetlet.2016.12.066
- ISSN
- 0040-4039
- Abstract
- A new Cu2+-selective colorimetric sensor was developed by combining the chromophore 3-hydroxynaphthalimide with diaminomaleonitrile. The sensor showed Cu2+-selective colorimetric signaling behavior in dimethylsulfoxide, indicated by a solution color change from yellow to pink, which was readily discernible without any external devices. Practical application of the sensor to the detection of Cu2+ in an aqueous solution containing other environmentally relevant metal ions by selective two-phase liquid-liquid extraction with ethyl acetate was possible. Particularly, extractive signaling of Cu2+ in simulated semiconductor wastewater with a readily-usable smartphone as a colorimetric data capture and analysis tool was successfully conducted. (C) 2016 Elsevier Ltd. All rights reserved.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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