Complementary Reactivity in Selective Radical Processes: Electrochemistry of Oxadiazolines to Quinazolinones
- Authors
- Hwang, Ho Seong; Cho, Eun Jin
- Issue Date
- Jul-2021
- Publisher
- American Chemical Society
- Citation
- Organic Letters, v.23, no.13, pp 5148 - 5152
- Pages
- 5
- Journal Title
- Organic Letters
- Volume
- 23
- Number
- 13
- Start Page
- 5148
- End Page
- 5152
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/49019
- DOI
- 10.1021/acs.orglett.1c01676
- ISSN
- 1523-7060
1523-7052
- Abstract
- Electrochemistry has recently emerged as a sustainable approach for efficiently generating radical intermediates utilizing eco-friendly electric energy. An electrochemical process was developed to transform 1,2,4-oxadiazolines under mild conditions. The electrochemical N-O bond cleavage at a controlled oxidation potential led to the selective synthesis of quinazolinone derivatives that could not be obtained by photocatalytic radical processes, indicating complementary reactivities in radical processes. The electrochemical reaction pathways were fully revealed by density functional theory-based investigations. ©
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