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ortho-Naphthoquinone-catalyzed aerobic oxidation of amines to fused pyrimidin-4(3H)-ones: a convergent synthetic route to bouchardatine and sildenafil
- Authors
- Kim, Kyeongha; Kim, Hun Young; Oh, Kyungsoo
- Issue Date
- Aug-2020
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- RSC ADVANCES, v.10, no.52, pp 31101 - 31105
- Pages
- 5
- Journal Title
- RSC ADVANCES
- Volume
- 10
- Number
- 52
- Start Page
- 31101
- End Page
- 31105
- ISSN
- 2046-2069
2046-2069
- Abstract
- A facile access to fused pyrimidin-4(3H)-one derivatives has been established by using the metal-freeortho-naphthoquinone-catalyzed aerobic cross-coupling reactions of amines. The utilization of two readily available amines allowed a direct coupling strategy to quinazolinone natural product, bouchardatine, as well as sildenafil (Viagra (TM)) in a highly convergent manner.
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