Strongly Coupled Tin(IV) Sulfide-MultiWalled Carbon Nanotube Hybrid Composites and Their Enhanced Thermoelectric Properties

Abstract

Herein, tin(IV) sulfide (SnS2) and multiwalled carbon nanotube (MWCNT) composites are fabricated via a simple solution-mixing method in a hydrothermal reactor. SnS2 is closely coupled to the MWCNT surface, thus forming a coaxial nanostructure. Examination by X-ray photoelectron spectroscopy and scanning transmission electron microscopy indicates that the strong interface between SnS2 and the MWCNTs in the composite material is due to the formation of Sn-O and Sn-S bonds. In addition, an examination of the temperature-dependent thermoelectric (TE) properties demonstrates that the SnS2-MWCNT hybrid composite with 3 wt % MWCNTs exhibits the maximum power factor of ∼91.34 μW/(m·K2) at 500 K, which is ∼50 times larger than that of the pristine SnS2. These results highlight the fabrication and enhanced TE properties of hybrid composites via the coupling of SnS2 and MWCNTs. © 2022 American Chemical Society.