100th Anniversary of Macromolecular Science Viewpoint: Opportunities for Liquid Crystal Polymers in Nanopatterning and Beyond

Abstract

Liquid-crystal polymers (LCPs) integrate at a molecular level the characteristics of two important material classes, i.e., liquid crystals (LCs) and polymers. As a result, they exhibit a wide variety of intriguing physical phenomena and have useful properties in various settings. In the nearly 50 years since the discovery of the first meltprocessable LCPs, there has been a remarkable expansion in the field encompassing the development of new chain architectures, the incorporation of new classes of mesogens, and the exploration of new properties and applications. As engineering materials, LCPs are historically best known in the context of high strength fibers. In a more contemporary study, the pairing of LC mesophase assembly with block copolymer (BCP) self-assembly in LC BCPs has resulted in a fascinating interplay of ordering phenomena and rich phase behavior, while lightly crosslinked networks, LC elastomers, are extensively investigated as shape memory materials based on their thermomechanical actuation. As this Viewpoint describes, these and other examples are active areas of research in which new, compelling opportunities for LCPs are emerging. We highlight a few selected areas that we view as being potentially significant in the near future, with a particular emphasis on nanopatterning. Here, the ability to readily access small feature sizes, the fluidity of the LC mesophase, and LC-based handles for achieving orientation control present a compelling combination. Opportunities for LCPs are also presented under the broad rubric of "beyond nanopatterning", and we discuss relevant challenges and potential new directions in the field.