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CO2 hydrogenation into formate and methyl formate using Ru molecular catalysts supported on NNN pincer porous organic polymers
- Issue Date
- 7-Apr-2021
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- INORGANIC CHEMISTRY FRONTIERS, v.8, no.7, pp 1727 - 1735
- Pages
- 9
- Journal Title
- INORGANIC CHEMISTRY FRONTIERS
- Volume
- 8
- Number
- 7
- Start Page
- 1727
- End Page
- 1735
- ISSN
- 2052-1553
2052-1553
- Abstract
- NNN pincer incorporated porous organic polymers (POPs) were prepared using a facile knitting method of pyridine based ligands via the Friedel-Crafts reaction. Ru-based molecular catalysts supported on the prepared POPs were implemented for catalytic CO2 hydrogenation into formate and methyl formate. In particular, a heterogeneous Ru/N-Me-3-bpp-POP catalyst exhibited the maximum catalytic conversion of CO2 into formate, with a turnover number (TON) of 1877, and into methyl formate with a TON of 2197. In addition, the stability of the Ru/N-Me-3-bpp-POP catalyst was demonstrated over five successive runs with a slight decrease in the catalytic efficiency, which may originate from Ru leaching.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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