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Absolute metastable limit of liquids and gas-liquid solutions

Authors
Kwak, H.-Y.Kim, H.-W.Ko, I.
Issue Date
2010
Publisher
American Society of Mechanical Engineers (ASME)
Citation
ASME International Mechanical Engineering Congress and Exposition, Proceedings, v.9, no.PART C, pp 1845 - 1852
Pages
8
Journal Title
ASME International Mechanical Engineering Congress and Exposition, Proceedings
Volume
9
Number
PART C
Start Page
1845
End Page
1852
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/65105
DOI
10.1115/IMECE2009-10046
ISSN
0000-0000
Abstract
The absolute metastable limit, a one molecule critical cluster formation in the nucleation theory, was obtained by a thermodynamic stability analysis. The tensile strength values obtained for several organic liquids by centrifugal method turned out to be about 50% of the absolute metastable limit, while the tensile strength of water, measured in microscopic inclusions, is close to the absolute metastable limit. On the other hand, the tensile strength values estimated at the superheat limit was about 17% of the absolute limit and the decompression amount for gas bubble formation is about 12% of the absolute limit. Copyright © 2010 by ASME.
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