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Structural and dielectric behavior or Ba-substituted Pb(Yb1/2Nb1/2)O-3 ceramics

Authors
Kim, J.H.Kim, H.S.Koh, K.S.Shim, I.W.Choo, W.K.
Issue Date
Oct-2002
Publisher
TAYLOR & FRANCIS LTD
Keywords
Dielectric; Antiferroelectric; Ferroelectric; perovskite; relaxor to normal; relaxor
Citation
INTEGRATED FERROELECTRICS, v.47, pp 3 - 10
Pages
8
Journal Title
INTEGRATED FERROELECTRICS
Volume
47
Start Page
3
End Page
10
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/65945
DOI
10.1080/10584580190044461
ISSN
1058-4587
1607-8489
Abstract
The crystal structure and the dielectric properties of the antiferroelectric solid solution of (1-x)Pb(Yb1/2Nb1/2)O-3-xBa(Yb1/2Nb1/2)O-3(Pb1-xBaxYN) (0 less than or equal to x less than or equal to 0.30) have been studied. The crystal structure is shown to become pseudocubic from the PYN's orthorhombic structure on solutionizing for x >0.5 while the transition shows a normal first-order paraelectric(PE)-antiferroelectric(AFE) behavior increasing x<0.14. The transition temperature gradually decreases with the increasing Ba2+ concentration. In the composition range 0.16 square x square 0.30, a typical relaxor behavior is displayed.
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