Exploring the Dominant Role of Atomic- and Nano-Ruthenium as Active Sites for Hydrogen Evolution Reaction in Both Acidic and Alkaline Media
DC Field | Value | Language |
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dc.contributor.author | Zhang, Lijie | - |
dc.contributor.author | Jang, Haeseong | - |
dc.contributor.author | Wang, Yan | - |
dc.contributor.author | Li, Zijian | - |
dc.contributor.author | Zhang, Wei | - |
dc.contributor.author | Kim, Min Gyu | - |
dc.contributor.author | Yang, Dongjiang | - |
dc.contributor.author | Liu, Shangguo | - |
dc.contributor.author | Liu, Xien | - |
dc.contributor.author | Cho, Jaephil | - |
dc.date.accessioned | 2024-01-08T06:29:54Z | - |
dc.date.available | 2024-01-08T06:29:54Z | - |
dc.date.issued | 2021-08 | - |
dc.identifier.issn | 2198-3844 | - |
dc.identifier.issn | 2198-3844 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/69287 | - |
dc.description.abstract | Ru nanoparticles (NPs) and single atoms (SAs)-based materials have been investigated as alternative electrocatalysts to Pt/C for hydrogen evolution reaction (HER). Exploring the dominant role of atomic- and nano-ruthenium as active sites in acidic and alkaline media is very necessary for optimizing the performance. Herein, an electrocatalyst containing both Ru SAs and NPs anchored on defective carbon (RuSA+NP/DC) has been synthesized via a Ru-alginate metal-organic supramolecules conversion method. RuSA+NP/DC exhibits low overpotentials of 16.6 and 18.8 mV at 10 mA cm(-2) in acidic and alkaline electrolytes, respectively. Notably, its mass activities are dramatically improved, which are about 1.1 and 2.4 times those of Pt/C at an overpotential of 50 mV in acidic and alkaline media, respectively. Theoretical calculations reveal that Ru SAs own the most appropriate H* adsorption strength and thus, plays a dominant role for HER in acid electrolyte, while Ru NPs facilitate the dissociation of H2O that is the rate-determining step in alkaline electrolyte, leading to a remarkable HER activity. | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY | - |
dc.title | Exploring the Dominant Role of Atomic- and Nano-Ruthenium as Active Sites for Hydrogen Evolution Reaction in Both Acidic and Alkaline Media | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/advs.202004516 | - |
dc.identifier.bibliographicCitation | ADVANCED SCIENCE, v.8, no.15 | - |
dc.description.isOpenAccess | Y | - |
dc.identifier.wosid | 000657692600001 | - |
dc.identifier.scopusid | 2-s2.0-85107129092 | - |
dc.citation.number | 15 | - |
dc.citation.title | ADVANCED SCIENCE | - |
dc.citation.volume | 8 | - |
dc.type.docType | Article | - |
dc.publisher.location | 미국 | - |
dc.subject.keywordAuthor | electrocatalysts | - |
dc.subject.keywordAuthor | hydrogen evolution reaction | - |
dc.subject.keywordAuthor | metal-organic supramolecules | - |
dc.subject.keywordAuthor | ruthenium | - |
dc.subject.keywordAuthor | single atoms | - |
dc.subject.keywordPlus | EGG-BOX | - |
dc.subject.keywordPlus | OXYGEN REDUCTION | - |
dc.subject.keywordPlus | ELECTROCATALYSTS | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | ALGINATE | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | PH | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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