Radical-Mediated Fluoroalkylations
- Authors
- Cho, Eun Jin
- Issue Date
- Feb-2016
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- fluoroalkylation; inorganic electrides; photocatalysis; radical reactions; visible light
- Citation
- CHEMICAL RECORD, v.16, no.1, pp 47 - 63
- Pages
- 17
- Journal Title
- CHEMICAL RECORD
- Volume
- 16
- Number
- 1
- Start Page
- 47
- End Page
- 63
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/7330
- DOI
- 10.1002/tcr.201500215
- ISSN
- 1527-8999
1528-0691
- Abstract
- Recently, the development of eco-friendly radical processes has become of great interest in synthetic chemistry. In particular, visible-light photocatalysis has drawn tremendous attention for its environmental compatibility and versatility in promoting many synthetically important reactions. In addition, inorganic electrides as electron donors have emerged as new eco-friendly tools for radical transformations since they consist of non-toxic and naturally abundant main metals such as calcium. The design of new fluoroalkylation reactions has benefited greatly from recent advances in visible-light photocatalysis and the chemistry of inorganic electrides. Since adding fluoroalkyl groups can dramatically change the physical and chemical properties of organic compounds, using these processes to promote eco-friendly radical fluoroalkylations will have a major impact in areas such as pharmaceuticals, agrochemicals, and material sciences. This Personal Account reviews radical-mediated fluoroalkylations, such as trifluoromethylations and difluoroalkylations, recently developed in our laboratory.
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