Nickel-Catalyzed Double Deoxygenative C-N Coupling of Acyloxyamines
- Authors
- Ali, Kashif; Cho, Eun Jin
- Issue Date
- Jun-2024
- Publisher
- AMER CHEMICAL SOC
- Citation
- Organic letters, v.26, no.24, pp 5192 - 5195
- Pages
- 4
- Journal Title
- Organic letters
- Volume
- 26
- Number
- 24
- Start Page
- 5192
- End Page
- 5195
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/74727
- DOI
- 10.1021/acs.orglett.4c01758
- ISSN
- 1523-7060
1523-7052
- Abstract
- A double deoxygenative C-N coupling protocol has been developed by employing acyloxyamines through N-O bond activation. The C-N bond formation under mild reaction conditions, employing NiCl2 as the catalyst and cataCXiumA as a ligand, results in the production of a diverse array of alkylated secondary or tertiary amines, including heterocyclic amines. This method introduces a novel catalytic strategy that emphasizes the versatility of nickel-catalyzed reactions, extending beyond traditional synthetic boundaries.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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