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Hydrothermal self - sacrificing growth of polymorphous MnO2 on magnetic porous - carbon (Fe3O4@Cg/MnO2): A sustainable nanostructured catalyst for activation of molecular oxygen

Authors
Bakhtiarzadeh, Z.Rouhani, ShamilaKarimi, ZibaRostamnia, SadeghMsagati, Titus M.Kim,DokyoonJang, Ho WonRamakrishna, SeeramVarma, Rajender S.Shokouhimehr, Mohammadreza
Issue Date
Jun-2021
Publisher
Elsevier B.V.
Keywords
Alcohol oxidation; Magnetic nanoparticles; MnO2; Nanostructured catalyst
Citation
Molecular Catalysis, v.509, pp.1 - 8
Indexed
SCIE
SCOPUS
Journal Title
Molecular Catalysis
Volume
509
Start Page
1
End Page
8
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/105763
DOI
10.1016/j.mcat.2021.111603
ISSN
2468-8231
Abstract
Novel core-shell carbon coated-magnetic (Fe3O4@Cg) nanoparticles supported MnO2 nanosheets (with α- and β-type structure) (Fe3O4@Cg/MnO2) are synthesized through a self-sacrificing templet method. The new hybrid material was fully characterized with Fourier transformed infrared spectroscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy, X-ray diffraction analysis (XRD), N2 adsorption/desorption analysis, and transmission electron microscopy; XRD and SEM results affirmed that α- and β-MnO2 nanosheets polymorphs onto the Fe3O4@Cg. The catalytic activity of the as-prepared nanostructured catalyst Fe3O4@Cg/MnO2 has been evaluated in O2 activation for the selective oxidation of benzyl alcohol to benzaldehyde with high conversion; it stability being confirmed by the recycling of the nanostructured catalyst with no obvious loss even after six repeated runs. © 2021
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ERICA 첨단융합대학 (ERICA 바이오나노공학전공)
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