Metal-organic framework-based nanostructured catalysts: Applications in efficient organic transformations
- Authors
- Xia, Changlei; Wu, Jiamin; Delbari, Seyed Ali; Namini, Abbas Sabahi; Yuan, Yan; Van Le, Quyet; Kim, Dokyoon; Varma, Rajender S.; T-Raissi, Ali; Jang, Ho Won; Shokouhimehr, Mohammadreza
- Issue Date
- Jul-2023
- Publisher
- Elsevier
- Keywords
- Metal -organic frameworks; Organic reaction; Catalysis; Nanocatalyst; Green process; Cross -coupling reaction
- Citation
- Molecular Catalysis, v.546, pp 1 - 26
- Pages
- 26
- Indexed
- SCIE
SCOPUS
- Journal Title
- Molecular Catalysis
- Volume
- 546
- Start Page
- 1
- End Page
- 26
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/112990
- DOI
- 10.1016/j.mcat.2023.113217
- ISSN
- 2468-8231
- Abstract
- In the heterogeneous catalyst domain, there has been an incessant demand in recent decades with a focus on introducing environmentally friendly and sustainable materials. Because of their distinct structural properties, metal-organic frameworks (MOFs) are emerging as a new class of active materials for organic reactions; sophisticated hybrid catalytic materials can now be fabricated with improved recyclability, separability, and activity for specific organic processes by integrating MOFs with metallic nanoparticles. Herein, we deliberate on several MOF-based nanostructured catalysts that facilitate selected organic transformations. Examples comprise, among others, the Baeyer-Villiger oxidation, cyanation of aldehydes, cycloalkane oxidation, epoxidation of cyclohexenes, esterification, Heck reaction, tandem reactions, Sonogashira and Suzuki-Miyaura cross-coupling reactions, which exploit the catalysts' reactivity, reusability, and interactions with the inherent properties of the deployed MOF-based nanostructured catalysts. The benefits, shortcomings, reusability, and efficiency aspects of the introduced catalysts are reviewed. A succinct conclusion is offered, along with a commentary on the major hurdles encountered today and prospective future research needs related to the MOF-based catalysts.
- Files in This Item
-
Go to Link
- Appears in
Collections - COLLEGE OF ENGINEERING SCIENCES > DEPARTMENT OF BIONANO ENGINEERING > 1. Journal Articles
![qrcode](https://api.qrserver.com/v1/create-qr-code/?size=55x55&data=https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/112990)
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.