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하수슬러지의 수열탄화를 통한 고형연료 탄화 특성Solid Fuel Carbonization Characteristics through Hydrothermal Carbonization of Sewage Sludge

Other Titles
Solid Fuel Carbonization Characteristics through Hydrothermal Carbonization of Sewage Sludge
Authors
한성국김문일
Issue Date
Jun-2023
Publisher
유기성자원학회
Keywords
Hydrothermal Carbonization(HTC); Sewage Sludge; Degree of Carbonization; Fuel ratio; Solid-Fuel; 수열탄화; 하수슬러지; 탄화도; 연료비; 고형연료
Citation
유기물자원화, v.31, no.2, pp 53 - 61
Pages
9
Indexed
KCI
Journal Title
유기물자원화
Volume
31
Number
2
Start Page
53
End Page
61
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/113576
DOI
10.17137/korrae.2023.31.2.53
ISSN
1225-6498
2508-3015
Abstract
하수슬러지의 대부분은 생물학적 처리에 의한 미생물에 의해 분해 가능한 유기물질을 다량 함유하고 있는유기성 폐기물이다. 기존의 하수슬러지 처리방법으로는 건조, 소각, 반탄화 그리고 탄화 등의 기술을 이용하여감량화 및 연료화를 진행하고 있다. 그러나, 건조를 기반으로 하여 539kcal/kg의 잠열이 소비됨으로 에너지 소비가높은 단점이 지적되고 있다. 따라서 본 연구에서는 열화학적 처리인 수열탄화(HTC)를 통해 고형연료를 생산하고자한다. 고형연료의 가치를 평가하기 위하여 탄화도 및 연료비의 특성을 분석하였다. 그 결과 수열탄화 반응온도가증가할수록 탄화도의 상승으로 저위발열량도 약 500kcal/kg 상승하였다. H/C, O/C, Ratio는 1.78, 0.46에서 1.57, 0.32로감소하는 경향을 보였다. 건조슬러지의 가연분(고정탄소+휘발분) 대비 회분(Ash)의 비율이 0.25 이상으로 나타날경우는 수열탄화를 진행하여도 탄화도 및 발열량의 증가되지 않는다는 것을 도출하였다.
Most of the sewage sludge is organic waste containing a large amount of organic substances decomposable by microorganisms by biological treatment. As for existing sewage sludge treatment methods, reduction and fuel conversion are being carried out using technologies such as drying, incineration, torrefaction, carbonization. However, the disadvantage of high energy consumption has been pointed out as latent heat of 539 kcal/kg is consumed based on drying. Therefore, in this study, we intend to produce solid fuel through hydrothermal carbonization(HTC), which is a thermochemical treatment. To evaluate the value of solid fuel, the characteristics of carbonization and fuel ratio were analyzed. As a result, as the hydrothermal carbonization reaction temperature increased, the lower heating value also increased by about 500 kcal/kg due to the increase in the degree of carbonization. H/C, O/C, ratio showed a decreasing trend from 1.78, 0.46 to 1.57, 0.32. When the ratio of ash to combustible content (fixed carbon + volatile) of dry sludge was 0.25 or more, it was derived that the degree of carbonization and calorific value did not increase even when hydrothermal carbonization was performed.
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ERICA 공학대학 (DEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING)
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