Detailed Information
Cited 0 time in 
Cited 0 time in 
Cited 0 time in
Metadata Downloads
Postsynthetic ion exchange and characterization of alkali metal ions ordered in the pores of anionic Zr metal–organic framework
- Authors
- 전형필
- Issue Date
- Oct-2021
- Publisher
- 대한화학회
- Keywords
- alkali metal; dobdc; Ion exchange; MOF; zirconium
- Citation
- Bulletin of the Korean Chemical Society, v.42, no.10, pp 1357 - 1363
- Pages
- 7
- Indexed
- SCIE
SCOPUS
KCI
- Journal Title
- Bulletin of the Korean Chemical Society
- Volume
- 42
- Number
- 10
- Start Page
- 1357
- End Page
- 1363
- ISSN
- 0253-2964
1229-5949
- Abstract
- Binding alkali metal ions in solutions is an important yet difficult task and it is especially true for a solid host in aqueous systems. This study shows that a water stable, anionic metal–organic framework (Zr-dobdc) is capable of capturing M+ (M = Li, Na, K, Rb, and Cs) ions dissolved in water through ion exchange. The alkali metal ions captured at the unique cation-binding pockets of Zr-dobdc and their ordered alignments in the crystal lattice are unambiguously characterized by X-ray single-crystal and powder diffraction studies. The apparent selectivity for alkali metal ions over other metal ions is also explained. © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH
- Files in This Item
- Go to Link
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Related Researcher
- Chun, Hyungphil
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)