Enhancement of the Oxygen Evolution Using a 21-mu m-Thin c-Si Photoanode with a Nano-Pyramid Texture
- Authors
- Park, Min-Joon; Heo, Jong; Jee, Hongsub; Yu, Jin Young; Youn, Sungmin; Jeon, Kiseok; Lee, Jung-Ho; Jeong, Chaehwan
- Issue Date
- Dec-2017
- Publisher
- Electrochemical Society, Inc.
- Keywords
- SILICON SOLAR-CELLS; WATER; PHOTOELECTRODES; NANOPARTICLES; PHOTOCATHODES; ELECTROLYSIS; FILMS; XPS; Si nanopyramid; thin c-Si photoanode; water splitting
- Citation
- Journal of the Electrochemical Society, v.164, no.14, pp.H1129 - H1132
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of the Electrochemical Society
- Volume
- 164
- Number
- 14
- Start Page
- H1129
- End Page
- H1132
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/12050
- DOI
- 10.1149/2.1251714jes
- ISSN
- 0013-4651
- Abstract
- It is beneficial to reduce thickness of high-purity of c-Siwafer for cost-effective water splitting system based on silicon photoelectrode. However, a thin Si absorber causes insufficient absorption of light and it should be needed to solve problems. Here, a 21-mu m-thin Si photoanode for which a NiOx-coated silicon nanopyramid (SiNP) is employed is presented as a solution. The NiOx/n-SiNP structures improved the light absorption as well as the total number of catalytic sites to enable photo-oxidation reactions. A photocurrent of 7.7 mA/cm(2) was generated at the equilibrium potential of the OER (E-OER = 1.23 V vs. a reversible hydrogen electrode in a 1 M KOH solution). Also, the photoanode did not show any degradation over the 24 hr of a photoelectrochemical water-oxidation process. (c) 2017 The Electrochemical Society. All rights reserved.
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