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Synthesis of Cobalt Cluster-based Supramolecular Triple-Stranded Helicates

Authors
Yoo, Hyo jongLee, JeongheeKang, PhiljaeChoi, Moon-Gun
Issue Date
Aug-2015
Publisher
Royal Society of Chemistry
Citation
Dalton Transactions, v.44, no.32, pp.14213 - 14216
Indexed
SCIE
SCOPUS
Journal Title
Dalton Transactions
Volume
44
Number
32
Start Page
14213
End Page
14216
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/17498
DOI
10.1039/c5dt01895a
ISSN
1477-9226
Abstract
A cobalt cluster-based triple-stranded helicate, Co8(PDA)6(PTA)3(DMF)3(H2O)3 (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co8(PDA)6(PTA)3(DMF)2(H2O)4-0.51(Co(OHn)2)] (n = 1 or 2) (2).
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Yoo, Hyo jong
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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