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Protonic Conduction Properties of Nanostructured Gd-doped CeO2 at Low Temperatures

Authors
Park, Hee JungShin, Jae SooChoa, Yong HoSong, Han BokLee, Ki MoonLee, Kyu Hyoung
Issue Date
Dec-2015
Publisher
KOREAN CERAMIC SOC
Keywords
Nanostructure; Protonic conductor; Ceria
Citation
Journal of the Korean Ceramic Society, v.52, no.6, pp.527 - 530
Indexed
SCOPUS
KCI
Journal Title
Journal of the Korean Ceramic Society
Volume
52
Number
6
Start Page
527
End Page
530
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/20676
DOI
10.4191/kcers.2015.52.6.527
ISSN
1229-7801
Abstract
The electrical properties of nanostructured Gd-doped CeO2 (n-GDC) as a function of temperature and water partial-pressure were investigated using ac and dc measurements. For n-GDC, protonic conductivity prevails under wet condition and at low temperatures (< 200 degrees C), while oxygen ionic conductivity occurs at high temperatures (>200 degrees C) under both dry and wet conditions. The grain boundaries in n-GDC were highly selective, being conductive for protonic transport but resistive for oxygen ionic transport. The protonic conductivity reaches about 4 x 10(-7) S/cm at room temperature (RT).
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ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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