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Synthesis of CdSe/ZnSe quantum dots passivated with a polymer for oxidation prevention

Authors
Kwon, Young-TaeChoi, Yo-MinKim, Ka-HeeLee, Chan-GiLee, Kun-JaeKim, Bum-SungChoa, Yong-Ho
Issue Date
Nov-2014
Publisher
ELSEVIER SCIENCE SA
Keywords
PMMA coating; Dispersion stability; Fluorescence stability; Oxidation; Degradation
Citation
SURFACE & COATINGS TECHNOLOGY, v.259, pp.83 - 86
Indexed
SCIE
SCOPUS
Journal Title
SURFACE & COATINGS TECHNOLOGY
Volume
259
Start Page
83
End Page
86
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/21123
DOI
10.1016/j.surfcoat.2014.05.061
ISSN
0257-8972
Abstract
Surface overcoated CdSe/ZnSe core/shell structured quantum dots (QDs) with enhanced stability, narrow size distribution and strong photoluminescence have been successfully synthesized by using a simple poly(methylmethacrylate) (PMMA) coating on nanoparticles. When applied to the surface of QDs, the polymer coating provided ultra-dispersion stability and a high fluorescence quantum yield of above 80% that prevented chemical degradation, such as aggregation and Ostwald ripening. The degree of degradation was measured with respect to storage time (1, 7, 15, and 30 days) in order to provide a comparison between PMMA uncoated and coated QDs, and the oxidation of QDs was confirmed with Fourier transform infrared spectroscopy. (C) 2014 Elsevier B.V. All rights reserved.
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CHOA, YONG HO
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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