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Pd nanoparticles immobilized on poly(NIPAM-co-4-VP) hydrogel: Highly active and reusable catalyst for carbon-carbon coupling reactions in water
- Issue Date
- Oct-2014
- Publisher
- Elsevier BV
- Keywords
- Pd nanoparticles; Poly(NIPAM-co-4-VP) co-polymers; Suzuki-Miyaura reaction; Heck-Mizoroki reaction; Sonogashira coupling reaction; Water
- Citation
- Journal of Organometallic Chemistry, v.769, pp.80 - 93
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of Organometallic Chemistry
- Volume
- 769
- Start Page
- 80
- End Page
- 93
- ISSN
- 0022-328X
- Abstract
- Poly(N-isopropylacrylamide-co-4-vinylpyridine) [poly(NIPAM-co-4-VP)] co-polymer exhibited inverse temperature solubility with a lower critical solution temperature (LCST) in water. Pd nanoparticles were immobilized on these poly(NIPAM-co-4-VP) hydrogels. The heterogeneous Pd catalyst showed high catalytic activities for carbon-carbon coupling reactions, such as Suzuki-Miyaura, Heck-Mizoroki, and Sonogashira coupling reactions in water. The Pd catalyst immobilized on poly(NIPAM-co-4-VP) hydrogel (NIPAM:4-VP = 1:1 M ratio) showed an excellent recyclability and excellent yield for carbon-carbon coupling reactions. (c) 2014 Elsevier B.V. All rights reserved.
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Related Researcher
- Rhee, Hak june
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)