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Bistable and Porous Metal-Organic Frameworks with Charge-Neutral acs Net Based on Heterometallic M3O(CO2)(6) Building Blocks
- Authors
- Hong, Keunil; Bak, Woojeong; Moon, Dohyun; Chun, Hyungphil
- Issue Date
- Sep-2013
- Publisher
- American Chemical Society
- Keywords
- TOPOLOGY; ADSORPTION CAPACITY; MOFS; SEPARATION; CAPTURE
- Citation
- Crystal Growth & Design, v.13, no.9, pp.4066 - 4070
- Indexed
- SCIE
SCOPUS
- Journal Title
- Crystal Growth & Design
- Volume
- 13
- Number
- 9
- Start Page
- 4066
- End Page
- 4070
- ISSN
- 1528-7483
- Abstract
- A Co(II)-Ti(IV) heterometallic approach is successfully adopted to synthesize charge-neutral metal-organic frameworks based on oxo-centered trinuclear cluster and linear dicarboxylate linkers. Unlike their homonuclear predecessors, the cobalt-titanium-organic frameworks not only display a permanent porosity but also show an irreversible phase transition between two stable forms as unambiguously characterized by single-crystal and powder X-ray diffraction studies.
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Related Researcher
- Chun, Hyungphil
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)