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Unique Coordination-Based Heterometallic Approach for the Stoichiometric Inclusion of High-Valent Metal Ions in a Porous Metal-Organic Framework
- Authors
- Hong, Keunil; Bak, Woojeong; Chun, Hyungphil
- Issue Date
- May-2013
- Publisher
- American Chemical Society
- Keywords
- CARBOXYLATE; STABILITY; CO2; SITES; FLUE-GAS; SEPARATION; ADSORPTION; CARBON-DIOXIDE; CAPTURE; CATALYSTS
- Citation
- Inorganic Chemistry, v.52, no.10, pp.5645 - 5647
- Indexed
- SCIE
SCOPUS
- Journal Title
- Inorganic Chemistry
- Volume
- 52
- Number
- 10
- Start Page
- 5645
- End Page
- 5647
- ISSN
- 0020-1669
- Abstract
- A heterometallic metal-organic framework incorporating Zn2+ and Ti4+ is successfully synthesized. The unique coordination mode of each metal ion to 2-oxido-1,4-benzenedicarboxylate leads to Zn6Ti2 building blocks, which extend to form a double-walled primitive cubic net. This material possesses a permanent porosity and long-term stability.
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Related Researcher
- Chun, Hyungphil
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)