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An in-situ simultaneous SAXS and WAXS survey of PEBAX (R) nanocomposites reinforced with organoclay and POSS during uniaxial deformation

Authors
Kamal, TahseenPark, Soo-YoungChoi, Myong-ChanChang, Young-WookChuang, Wei-TsungJeng, U-Ser
Issue Date
Jul-2012
Publisher
ELSEVIER SCI LTD
Keywords
Poly(ether-b-amide); Organoclay; Trisilinolphenyl-POSS
Citation
POLYMER, v.53, no.15, pp.3360 - 3367
Indexed
SCIE
SCOPUS
Journal Title
POLYMER
Volume
53
Number
15
Start Page
3360
End Page
3367
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/32240
DOI
10.1016/j.polymer.2012.05.037
ISSN
0032-3861
Abstract
Poly(ether-block-amide) (PEBA), commercially known as PEBAX (R), nanocomposites filled with organically modified clay (Cloisite 30B) and trisilinolphenyl-polyhedral oligomeric silsesquioxane (tsp-POSS) were prepared by a melt mixing method, respectively. The structures of the nanocomposites were investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and in-situ simultaneous small and wide angle X-ray scatterings (SAXS and WAXS) during uniaxial deformation. The FT-IR spectra showed the hydrogen bonding between the fillers and the PEBA which helped to disperse the fillers in the polymer matrix. The crystallinities and mechanical properties of the nanocomposites were improved compared to the neat polymer. Their origins were studied with an in-situ simultaneous SAXS and WAXS technique during the uniaxial deformation. (c) 2012 Elsevier Ltd. All rights reserved.
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Chang, Young-Wook
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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