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Dissolution Mechanism of Indium in CaO-Al2O3-SiO2 Slag at Low Silica Region

Authors
Ko, Kyu YeolPark, Joo Hyun
Issue Date
Jun-2012
Publisher
ASM International
Keywords
Slags; Equilibration techniques; Slag basicity; Solubility; Reducing atmosphere; Dissolution mechanism; Oxygen partial pressure; Critical level; Indium; Dissolution; Silica
Citation
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, v.43, no.3, pp.440 - 442
Indexed
SCIE
SCOPUS
Journal Title
Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume
43
Number
3
Start Page
440
End Page
442
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/32661
DOI
10.1007/s11663-012-9649-z
ISSN
1073-5615
Abstract
The solubility of indium was measured in the low-silica region (< 20 mass pct SiO2) of the CaO-Al2O3-SiO2 system by a thermochemical equilibration technique. The dissolution mechanism of indium into the CaO-Al2O3-SiO2 slag at 1773 K (1500 A degrees C) under a reducing atmosphere was elucidated. The indium solubility increases in the calcium silicate-based flux and decreases in the calcium aluminate-based flux with increasing oxygen partial pressure. Also, the solubility was found to decrease initially with increasing slag basicity until the basicity reached a critical level after which the solubility increases. This behavior is believed to indicate that the indium dissolution mechanism changes according to the basicity of the slag.
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Park, Joo Hyun
ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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