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Thermodynamics of Inclusion Formation and Its Influence on the Corrosion ehavior of Cu Bearing Duplex Stainless Steels

Authors
Jeon, Soon-HyeokKim, Soon-TaeLee, In-SungPark, Joo-HyunKim, Kwang-TaeKim, Ji-SooPark, Yong-Soo
Issue Date
Mar-2011
Publisher
Japan Institute of Metals
Keywords
copper; duplex stainless steel; potentiostatic; scanning electron microscope (SEM); inclusion; pitting corrosion
Citation
Materials Transactions, v.52, no.3, pp 416 - 422
Pages
7
Indexed
SCI
SCIE
SCOPUS
Journal Title
Materials Transactions
Volume
52
Number
3
Start Page
416
End Page
422
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/38221
DOI
10.2320/matertrans.M2010355
ISSN
1345-9678
1347-5320
Abstract
To elucidate the thermodynamics of inclusion formation and its influence on the corrosion behavior of Cu bearing duplex stainless steels, potentiodynamic and potentiostatic polarization tests, a SEM-EDS analysis of inclusions, and thermodynamic calculations of the formation of inclusions were carried out. While the resistance to general corrosion of the noble copper contained alloy-1.5Cu in a deaerated 2 M H2SO4 was higher than that of the alloy-BASE, the resistance to pitting corrosion of copper contained alloy-1.5Cu in a deaerated 0.5 N HCl + 1N NaCl and 30 mass% NaCl was lower than that of the alloy-BASE due to an increase of interface areas between inclusions and matrix acting as preferential pit initiation sites. The thermodynamic calculation for the formation of Cr-containing oxide inclusions was in good agreement with the experimental results. [doi:10.2320/matertrans.M2010355]
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ERICA 첨단융합대학 (ERICA 신소재·반도체공학전공)
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