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Electrochemical synthesis of compositionally modulated FexPd1-x nanowires

Authors
Jeon, ByungjunYoon, SanghwaYoo, Bongyoung
Issue Date
Dec-2010
Publisher
Pergamon Press Ltd.
Keywords
FePd nanowire; Electrodeposition; Complexing agent; Compositionally modulated FePd nanowire
Citation
Electrochimica Acta, v.56, no.1, pp.401 - 405
Indexed
SCIE
SCOPUS
Journal Title
Electrochimica Acta
Volume
56
Number
1
Start Page
401
End Page
405
URI
https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/39283
DOI
10.1016/j.electacta.2010.08.062
ISSN
0013-4686
Abstract
FexPd1-x nanowires were electrodeposited by template-directed growth from ammonium citrate baths by adjusting the current density and metal ions concentration ratio (Fe2+:Pd2+). A higher current density and ion ratio led to the synthesis of the amorphous Fe-rich FePd nanowires, whereas nanocrystalline Pd-rich FePd nanowires could be obtained by the low ion ratio and current density. To minimize the longitudinal compositional modulation in high aspect ratio pores, pulse current were applied instead of direct current. Also, based on the ability to vary the composition of FePd by adjusting average current density, compositionally modulated FePd nanowires were synthesized at fixed duty cycle. (C) 2010 Elsevier Ltd. All rights reserved.
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ERICA 공학대학 (DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING)
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