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Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane
- Issue Date
- Feb-2010
- Publisher
- Georg Thieme Verlag
- Keywords
- Baylis-Hillman acetates; allyltributylstannane; bis-pi-allylpalladium; 1,5-diene; allylation
- Citation
- Synthesis, no.4, pp.661 - 665
- Indexed
- SCIE
SCOPUS
- Journal Title
- Synthesis
- Number
- 4
- Start Page
- 661
- End Page
- 665
- ISSN
- 0039-7881
- Abstract
- Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh3)(4) or Pd(dba)(2) as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.
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Related Researcher
- Rhee, Hak june
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)