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Hydrogen storage in Co-and Zn-based metal-organic frameworks at ambient temperature
- Issue Date
- Dec-2009
- Publisher
- Pergamon Press Ltd.
- Keywords
- Metal-organic framework; Hydrogen storage; Hydrogen adsorption; Specific surface area; Physisorption
- Citation
- International Journal of Hydrogen Energy, v.34, no.24, pp.9754 - 9759
- Indexed
- SCIE
SCOPUS
- Journal Title
- International Journal of Hydrogen Energy
- Volume
- 34
- Number
- 24
- Start Page
- 9754
- End Page
- 9759
- ISSN
- 0360-3199
- Abstract
- Hydrogen adsorption properties of some Co-and Zn-based Metal-Organic Framework (MOF) materials were studied at near ambient temperatures. Maximal hydrogen storage capacity of 0.75 wt% was found for a Zn-based material at 175 Bar hydrogen pressure and T = -4 degrees C. Hydrogen adsorption correlated linearly with BET surface area and strongly depends on temperature. Relatively low structural stability of some MOF's results in framework collapse during degassing and hydrogen adsorption measurements. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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Related Researcher
- Chun, Hyungphil
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)