Targeted Synthesis of a prototype MOF Based on Zn-4(O)(O2C)(6) Units and a Nonlinear Dicarboxylate Ligand
- Authors
- Chun, Hyungphil; Jung, Heejin
- Issue Date
- Jan-2009
- Publisher
- American Chemical Society
- Citation
- Inorganic Chemistry, v.48, no.2, pp.417 - 419
- Indexed
- SCIE
SCOPUS
- Journal Title
- Inorganic Chemistry
- Volume
- 48
- Number
- 2
- Start Page
- 417
- End Page
- 419
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/41431
- DOI
- 10.1021/ic801906e
- ISSN
- 0020-1669
- Abstract
- A surprisingly small number of topologies are known in metal-organic frameworks (MOFs) that possess Zn-4(O)(O2C)(6) building units. One of such MOFs having a simple, nonlinear dicarboxylate ligand, 5-methylisophthalate (mip), is targeted and successfully synthesized. The framework, [Zn-4(O)(mip)(3)], is based on a nonuniform, uninodal six-connected net and is featured by complicated meshlike pores with narrow passages. Gas sorption studies reveal the potentials as a prototype from which new MOFs having interesting properties can be derived.
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