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A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity
- Authors
- Dybtsev, Danil N.; Nuzhdin, Alexey L.; Chun, Hyungphil; Bryliakov, Konstantin P.; Talsi, Evgeniy P.; Fedin, Vladimir P.; Kim, Kimoon
- Issue Date
- Jan-2006
- Publisher
- John Wiley & Sons Ltd.
- Keywords
- chirality; heterogeneous catalysis; metal-organic frameworks; microporous materials; sorption
- Citation
- Angewandte Chemie - International Edition, v.45, no.6, pp.916 - 920
- Indexed
- SCIE
SCOPUS
- Journal Title
- Angewandte Chemie - International Edition
- Volume
- 45
- Number
- 6
- Start Page
- 916
- End Page
- 920
- ISSN
- 1433-7851
- Abstract
- A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal-organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. (Figure Presented).
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Related Researcher
- Chun, Hyungphil
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)