An empirical relationship between optical properties and the nuclear quadrupole coupling parameters in the boron sites in the nonlinear optical CsLiB6O10
- Authors
- Lim, Ae Ran; Kim, Ji Won; Yoon, Choon Sup
- Issue Date
- Jul-2003
- Publisher
- Institute of Pure and Applied Physics
- Keywords
- crystal growth; nuclear magnetic resonance; other optical materials
- Citation
- Journal of the Physical Society of Japan, v.72, no.7, pp.1774 - 1778
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of the Physical Society of Japan
- Volume
- 72
- Number
- 7
- Start Page
- 1774
- End Page
- 1778
- URI
- https://scholarworks.bwise.kr/erica/handle/2021.sw.erica/46679
- DOI
- 10.1143/JPSJ.72.1774
- ISSN
- 0031-9015
- Abstract
- The rotation patterns of the nuclear magnetic resonance of B-11 (I = 3/2) in a nonlinear optical CsLiB6O10 single crystal were measured in three mutually perpendicular crystal planes. We observed sixteen different spectra which could be divided into two groups corresponding to two kinds of boron atoms, B(1) and B(2), having different boron-oxygen rings and lying at crystallographically inequivalent sites. From these results, the quadrupole coupling constants and the asymmetry parameters were determined at room temperature for the first time. For the 4-coordinated B(1), e(2)qQ/h = 0.23 +/- 0.03 MHz and eta = 0.456 +/- 0.004, and for the 3-coordinated B(2), e(2)qQ/h = 2.58 +/- 0.03 MHz and eta = 0.276 +/- 0.004. The directions of the principal axes of the electric field gradient tensors were also determined. The spectra for the two groups have different principal values of the electric field gradient tensor and originate from magnetically inequivalent sites. The principal Z-axis of the EFG tensor nearly coincides with the normal to the plane of the boron-oxygen triangle. We found an interesting correlation between the asymmetry parameter and the largest nonlinear optical coefficient.
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