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Oxidative rearrangement of ketimines to amides by MCPBA and BF3-OEt2
- Authors
- Kim, So Yeon; An, Gwang-Il; Rhee, Hakjune
- Issue Date
- Jan-2003
- Publisher
- Georg Thieme Verlag
- Keywords
- oxidative rearrangement; ketimines; ketones; migratory aptitude; amides
- Citation
- Synlett, no.1, pp 112 - 114
- Pages
- 3
- Indexed
- SCIE
SCOPUS
- Journal Title
- Synlett
- Number
- 1
- Start Page
- 112
- End Page
- 114
- ISSN
- 0936-5214
1437-2096
- Abstract
- Several amides were obtained by an efficient method from the corresponding alkyl aryl ketimines in high yields. Ketimines are readily prepared from the corresponding ketones. This procedure involves the oxidation of alkyl aryl ketimines with MCPBA with BF3.OEt2. In this reaction, only aryl group of alkyl aryl ketimines was migrated to the electron deficient nitrogen atom.
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Related Researcher
- Rhee, Hak june
- ERICA 공학대학 (ERICA 에너지바이오학과)