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Copper(I)-Catalyzed Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Azidoformates and Aryl Terminal Alkynes
- Issue Date
- Apr-2018
- Publisher
- American Chemical Society
- Citation
- Journal of Organic Chemistry, v.83, no.8, pp.4805 - 4811
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of Organic Chemistry
- Volume
- 83
- Number
- 8
- Start Page
- 4805
- End Page
- 4811
- ISSN
- 0022-3263
- Abstract
- The copper(I)-catalyzed azide-alkyne cycloaddition reaction has been extensively studied and widely applied in organic synthesis. However, the formation of 1,2,3-triazoles with electron-deficient azide has been a challenging problem. In this report, we have demonstrated the formation of regioselective 1,4-disubstituted 1,2,3-triazoles from various types of aryl terminal alkynes and azidoformates, which are electron-deficient azides, using a commercialized [Cu-(CH3CN)(4)]PF6 copper(I) catalyst under mild conditions.
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Related Researcher
- Rhee, Hak june
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY (DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING)