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Molecular layer deposition of charge-transfer complex thin films with visible-light absorption
- Authors
- Jung, Jin Won; Han, Kyu S.; Yoon, Kwan Hyuck; Lee, Lynn; Lee, Yong-Eun Koo; Lee, Chi Ho; Lee, Sang Uck; Sung, Myung Mo
- Issue Date
- Jan-2018
- Publisher
- Elsevier BV
- Keywords
- Metal-organic complex; Ligand to metal charge transfer; Molecular layer deposition; Hydroquinone; Phototransistor
- Citation
- Organic Electronics, v.52, pp 237 - 242
- Pages
- 6
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- Organic Electronics
- Volume
- 52
- Start Page
- 237
- End Page
- 242
- ISSN
- 1566-1199
1878-5530
- Abstract
- A titanium-aryloxide (Ti-Ao) complex showing high visible-light absorption was fabricated by molecular layer deposition. Studies using ultraviolet-visible spectroscopy and density functional theory calculations revealed that the origin of the visible absorption was ligand-to-metal charge-transfer. ZnO/Ti-Ao nanolaminate photo-transistors functioned synergistically with Ti-Ao acting as a visible-light absorber, and ZnO serving as a good semiconductor.
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