Energy Transfer Photocatalytic Radical Rearrangement in N-Indolyl Carbonates
- Authors
- Bera, Milan; Hwang, Ho Seong; Um, Tae-Woong; Oh, Soo Min; Shin, Seunghoon; Cho, Eun Jin
- Issue Date
- Mar-2022
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.24, no.9, pp.1774 - 1779
- Indexed
- SCIE
SCOPUS
- Journal Title
- ORGANIC LETTERS
- Volume
- 24
- Number
- 9
- Start Page
- 1774
- End Page
- 1779
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/139265
- DOI
- 10.1021/acs.orglett.2c00085
- ISSN
- 1523-7060
- Abstract
- A new type of sp(3)-like N-centered radical has been generated by selective energy transfer catalysis. Upon photoexcitation, homolytic N-O bond cleavage of N-indolyl carbonate in the presence of an Ir complex produced N- and O- centered radicals. The high spin density at the C3 position of indole led to radical recombination with the O-centered radical, affording valuable 3-oxyindole derivatives without decarboxylation. Transformations of the desired products into various molecules were also demonstrated.
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