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Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
- Authors
- Youn, So Won; Kim, Byung Seok; Jagdale, Arun R.
- Issue Date
- Jul-2012
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.28, pp.11308 - 11311
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 134
- Number
- 28
- Start Page
- 11308
- End Page
- 11311
- ISSN
- 0002-7863
- Abstract
- A Pd(II)-catalyzed reaction engaging alkenyl beta-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium-(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki-Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first aromatization-driven beta-carbon elimination process. A single Pd catalyst served to promote a series of both C-C bond forming and cleavage events in an unprecedented manner.
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Related Researcher
- Youn, So Won
- COLLEGE OF NATURAL SCIENCES (DEPARTMENT OF CHEMISTRY)