Morphology Effect on Enhanced Li+-Ion Storage Performance for Ni2+/3+ and/or Co2+/(3+) Doped LiMnPO4 Cathode Nanoparticlesopen access
- Authors
- Yun, Young Jun; Wu, Mihye; Kim, Jin Kyu; Ju, Ji Young; Lee, Sun Sook; Kim, Ki Woong; Park, Woon Ik; Jung, Ha-Kyun; Kim, Kwang Ho; Park, Jin-Seong; Choi, Sungho
- Issue Date
- Nov-2015
- Publisher
- HINDAWI LTD
- Citation
- JOURNAL OF NANOMATERIALS, v.2015, pp.1 - 8
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF NANOMATERIALS
- Volume
- 2015
- Start Page
- 1
- End Page
- 8
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/155950
- DOI
- 10.1155/2015/970856
- ISSN
- 1687-4110
- Abstract
- The electrochemical performance of Li(Mn, M)PO4 (M = Co2+/3+, Ni2+/3+) was investigated with regard to the particle morphology. Within a controlled chemical composition, Li(Mn0.92Co0.04Ni0.04)PO4, the resultant cathode exhibited somewhat spherical-shaped nanocrystalline particles and enhanced Li+-ion storage, which was even better than the undoped LiMnPO4, up to 16% in discharge capacity at 0.05 C. The outstanding electrochemical performance is attributed to the well-dispersed spherical-shaped particle morphology, which allows the fast Li+-ion migration during the electrochemical lithiation/delithiation process, especially at high current density.
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