Pd-Catalyzed Regioselective Intramolecular Allylic C-H Amination of 1,1-Disubstituted Alkenyl Amines br
- Authors
- Kim, Young Ho; Kim, Dong Bin; Jang, Su San; Youn, So Won
- Issue Date
- Jun-2022
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v.87, no.11, pp.7574 - 7580
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 87
- Number
- 11
- Start Page
- 7574
- End Page
- 7580
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/170093
- DOI
- 10.1021/acs.joc.2c00781
- ISSN
- 0022-3263
- Abstract
- Pd-Catalyzed intramolecular allylic C-H aminationof 1,1-disubstituted alkenyl amines with various allylic tethers (X =O, NMs, CH2) was developed. This process allows for thedivergent synthesis of 1,3-X,N-heterocycles through a regioselectiveallylic C-H cleavage and pi-allylpalladium formation. Particularlynoteworthy is the use of substrates containing a labile allylic moietyand new simple catalytic systems capable of promoting highlychemo- and regioselective allylic C-H amination by overcomingsignificant challenges.
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