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Ferroelectric polarization-switching acceleration of sputtered Hf0.5Zr0.5O2 with defect-induced polarization of interlayer

Authors
Han, ChanghyeonYim, JiyongNguyen, AnKim, JeonghanKwon, Ki RyunKim, SangwooJeong, SoiPark, Eun ChanYou, Ji WonChoi, RinoKwon, Daewoong
Issue Date
Oct-2023
Publisher
Elsevier Ltd
Keywords
FeTFT; Hf< sub> 0.5< /sub> Zr< sub> 0.5< /sub> O< sub> 2< /sub> ; Polarization coupling; Sputtered HZO; TiO< sub> x< /sub> interlayer
Citation
Journal of Alloys and Compounds, v.960, pp.1 - 7
Indexed
SCIE
SCOPUS
Journal Title
Journal of Alloys and Compounds
Volume
960
Start Page
1
End Page
7
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/191964
DOI
10.1016/j.jallcom.2023.170516
ISSN
0925-8388
Abstract
Herein, ferroelectric properties of Hf0.5Zr0.5O2 (HZO) are analyzed by inserting various interlayers (ILs) underneath HZO in capacitors and ferroelectric thin-film-transistors (FeTFTs) with all-sputter-deposited metal/HZO/IL/Si (MFIS) stacks. Although all the HZO films have similar phase ratios regardless of the IL, only the MFIS stack with a TiOx IL exhibit polarization switching. To investigate the polarization due to the introduction of TiOx, the polarization of TiOx is checked. It is confirmed that the TiOx can be polarized by the movement of oxygen vacancies (OVs) depending on the electric-field direction, which accelerates the polarization switching of HZO. Therefore, the insertion of the TiOx IL results in a wide (3.4-V) memory window in the FeTFTs, since the IL suppress the leakage current by increasing the IL thickness and simultaneously accelerates the polarization switching of the HZO.
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