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Potassium Permanganate as Oxidizer in Alkaline Slurry for Chemical Mechanical Planarization of Nitrogen-doped Polycrystalline Ge2Sb2Te5 Film

Authors
Cui, HaoCho, Jong-YoungHwang, Hee-SubLim, Jae-HyungPark, Jin-HyungPark, Hyung SoonHong, KwonPark, Jea-Gun
Issue Date
Nov-2010
Publisher
ELECTROCHEMICAL SOC INC
Citation
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.157, no.11, pp H1036 - H1041
Indexed
SCI
SCIE
SCOPUS
Journal Title
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume
157
Number
11
Start Page
H1036
End Page
H1041
URI
https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/193944
DOI
10.1149/1.3486886
ISSN
0013-4651
1945-7111
Abstract
For phase-change memory beyond the 30 nm design rule, chemical mechanical planarization (CMP) performing at a high polishing rate, reasonable selectivity, and no corrosion-induced pits is essential for planarizing nitrogen-doped polycrystalline Ge2Sb2Te5 (GST) deposited on the confined memory cell structure. We develop a new alkaline slurry added with KMnO4 used as an oxidizer. The alkaline slurry added with 0.3 wt % KMnO4 has a polycrystalline GST film polishing rate of 5200 angstrom/min, a polishing rate selectivity between polycrystalline GST and SiO2 film of 100:1, and no corrosion-induced pit. In addition, polycrystalline GST film CMP using the alkaline slurry added with KMnO4 is observed to follow a cyclic reaction polishing mechanism.
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Park, Jea Gun
COLLEGE OF ENGINEERING (SCHOOL OF ELECTRONIC ENGINEERING)
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