A morphology, porosity and surface conductive layer optimized MnCo₂O₄ microsphere for compatible superior Li⁺ ion/air rechargeable battery electrode materialsA morphology, porosity and surface conductive layer optimized MnCo2O4 microsphere for compatible superior Li+ ion/air rechargeable battery electrode materials
- Other Titles
- A morphology, porosity and surface conductive layer optimized MnCo2O4 microsphere for compatible superior Li+ ion/air rechargeable battery electrode materials
- Authors
- Yun, Young Jun; Kim, Jin Kyu; Ju, Ji Young; Unithrattil, Sanjith; Lee, Sun Sook; Kang, Yongku; Jung, Ha-Kyun; Park, Jin-Seong; Im, Won Bin; Choi, Sungho
- Issue Date
- Feb-2016
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.45, no.12, pp.5064 - 5070
- Indexed
- SCIE
SCOPUS
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 45
- Number
- 12
- Start Page
- 5064
- End Page
- 5070
- URI
- https://scholarworks.bwise.kr/hanyang/handle/2021.sw.hanyang/23977
- DOI
- 10.1039/c5dt04975j
- ISSN
- 1477-9226
- Abstract
- Uniform surface conductive layers with porous morphology-conserved MnCo₂O₄ microspheres are successfully synthesized, and their electrochemical performances are thoroughly investigated. It is found that the microwave-assisted hydrothermally grown MnCo₂O₄ using citric acid as the carbon source shows a maximum Li⁺ ion lithiation/delithiation capacity of 501 mA h g⁻¹ at 500 mA g⁻¹ with stable capacity retention. Besides, the given microsphere compounds are effectively activated as air cathode catalysts in Li-O-2 batteries with reduced charge overpotentials and improved cycling performance. We believe that such an affordable enhanced performance results from the appropriate quasi-hollow nature of MnCo₂O₄ microspheres, which can effectively mitigate the large volume change of electrodes during Li⁺ migration and/or enhance the surface transport of the LiOx species in Li-air batteries. Thus, the rationally designed porous media for the improved Li⁺ electrochemical reaction highlight the importance of the 3D macropores, the high specific area and uniformly overcoated conductive layer for the promising Li⁺ redox reaction platforms.
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