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Synthesis and luminescent properties of bithiazole derivatives

Authors
Park, Jong-WookLee, Ji-HoonKho, Sam-IlKim, Tae Wan
Issue Date
Aug-2001
Publisher
ELSEVIER SCIENCE BV
Keywords
Photoluminescent; Bithiazole; Blue-emitting material
Citation
CURRENT APPLIED PHYSICS, v.1, no.2-3, pp.125 - 127
Journal Title
CURRENT APPLIED PHYSICS
Volume
1
Number
2-3
Start Page
125
End Page
127
URI
https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27196
DOI
10.1016/S1567-1739(01)00003-7
ISSN
1567-1739
Abstract
New blue photoluminescent materials 4,4'-bis(1-naphthyl)-2,2'-bithiazole (BNBT) and 4,4'-bis(4-biphenyl)-2,2'-bithiazole (BPBT) were synthesized by the facile reaction of 2-bromoacetoaromatic compound with dithioxamide. The resulting BNBT and BPBT having thiazole moiety were characterized by NMR, infrared (IR), UV/visible absorption and are well vacuum deposited for thin films. The BNBT and BPBT show blue photoluminescent (PL) spectra at 437 and 432 nm, respectively, and typical rectifying diode characteristics in ITO/BNBT or BPBT/Al device. The BNBT and BPBT are thermally stable up to 330 degrees C and 360 degrees C, respectively, under N-2. (c) 2001 Elsevier Science B.V. All rights reserved.
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