TEMPERATURE-DEPENDENT I-V CHARACTERISTICS AND THERMAL ANNEALING EFFECTS OF C-22-QUINOLIUM(TCNQ) LANGMUIR-BLODGETT-FILMS
- Authors
- KIM, TW; SHIN, DM; SONG, IS; KANG, DY; KWON, YS
- Issue Date
- 1994
- Publisher
- GORDON BREACH PUBLISHING, TAYLOR & FRANCIS GROUP
- Citation
- MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.247, pp.233 - 242
- Journal Title
- MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
- Volume
- 247
- Start Page
- 233
- End Page
- 242
- URI
- https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27733
- DOI
- 10.1080/10587259408039209
- ISSN
- 1058-725X
- Abstract
- Electrical properties and thermal annealing effects of C-22-quinolium(TCNQ) Langmuir-Blodgett(LB) films were studied. Typical current-voltage(I-V) characteristics along the perpendicular direction show an anomalous behavior of breakdown near the electric-field strength of 10(delta) V/cm. From the study of I-V characteristics in the high-electric field region, it is found that there is a contribution of joule heating in addition to the electrical effect. To see the thermal influence of the specimen, current was measured as a function of temperature(20 similar to 180 degrees C). It shows that the current increases about 4 orders of magnitude near 60 similar to 70 degrees C, and remains constant for a while up to similar to 150 degrees C and then suddenly drops. Such increase of current near 60 similar to 70 degrees C seems to be related to a softness of alkyl chains. Besides the electrical measurements, UV/visible absorption(300 similar to 800nm) of the thermally annealed sample was measured to see the internal-structure change. It is found there are four characteristic peaks. At 494nm, the optical absorption of the thermally annealed specimen at 60 degrees C starts to increase and stays almost constant upto similar to 140 degrees C. And eventually it disappears above 180 degrees C.
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Collections - College of Engineering > School of Electronic & Electrical Engineering > 1. Journal Articles
- College of Engineering > Chemical Engineering Major > 1. Journal Articles
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