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The Precursor Adsorption Mechanism, Growth Characteristics and Electrical Properties of Plasma-Enhanced Atomic Layer Deposited Tungsten Films by Using Tungsten Chloride Precursors

Authors
Seo, SeunggiLee, YujinOh, Il-KwonShong, BonggeunYoon, HwiLee, SanghunKim, Hyungjun
Issue Date
Jan-2020
Publisher
IEEE
Keywords
fluorine free tungsten; plasma-enhanced atomic layer deposition (PE-ALD); Tungsten chloride precursor; W films; Density Functional Theory
Citation
2020 IEEE INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE (IITC), pp.103 - 105
Journal Title
2020 IEEE INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE (IITC)
Start Page
103
End Page
105
URI
https://scholarworks.bwise.kr/hongik/handle/2020.sw.hongik/27987
DOI
10.1109/IITC47697.2020.9515589
ISSN
2380-632X
Abstract
Atomic layer deposited tungsten (W) films has been widely used in widespread applications due to its good characteristics such as low resistivity, high thermal and chemical stability. WF6 is the most commonly used precursor for vapor deposition of W. Hydrofluoric acid (HF) byproduct, etching of substrate and diffusion of fluorine could degrade device performance. To overcome these issues fluorine-free tungsten precursors have recently received attention. In this work, we fundamentally investigated PE-ALD process of W by using tungsten chloride (WClx) precursor and argon and hydrogen plasma. Developed W process could deposit W films with low Cl impurity and low resistivity.
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